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Highly active, entirely biobased antimicrobial Pickering emulsions
(Wiley, 2021-03-18)
We present the development of surfactant‐free, silica‐free and fully biobased oil‐in‐water antimicrobial Pickering emulsions, based on the self‐assembly of b ‐cyclodextrin and phytoantimicrobial oils (terpinen‐4‐ol or ...
Effect of hydrogen-bond strength on photoresponsive properties of polymer-azobenzene complexes
(NRC Research Press & Canadian Society for Chemistry, 2020-04-16)
Supramolecular complexation between photoresponsive azobenzene chromophores and a photopassive polymer host offers synthetic and design advantages compared with conventional covalent azo-containing polymers. In this context, ...
Molecular origin of the odd–even effect of macroscopic properties of n-Alkanethiolate self-assembled monolayers : bulk or interface?
(American Chemical Society, 2020-06-29)
Elucidating the influence of the monolayer interface versus bulk on the macroscopic properties (e.g., surface hydrophobicity, charge transport, and electron transfer) of organic self-assembled monolayers (SAMs) chemically ...
Electrospinning of highly crystalline polymers for strongly oriented fibers
(American Chemical Society, 2020-09-23)
Electrospun nanofibers (NFs) often demonstrate an exponential increase in mechanical and other properties at reduced diameters. Molecular orientation emerges as a key parameter for the performance of amorphous and low ...
Eumelanin : from molecular state to film
(American Chemical Society, 2021-02-02)
Eumelanin, a macromolecular biopigment, is an attractive candidate for sustainable (green) organic electronics. Establishing structure–property relationships in eumelanin films is an essential step to exploit its technological ...
Quantifying polymer chain orientation in strong and tough nanofibers with low crystallinity : towards next generation nanostructured superfibers
(American Chemical Society, 2019-04-19)
Advanced fibers revolutionized structural materials in the second half of the 20th century. However, all high-strength fibers developed to date are brittle. Recently, pioneering simultaneous ultrahigh strength and toughness ...
Photocontrol of supramolecular azo-containing block copolymer thin films during dip-coating : toward nanoscale patterned coatings
(American Chemical Society, 2019-05-07)
Dip-coating allows nanostructured block copolymer (BCP) thin film fabrication in a fast and facile one-step process. It can also be coupled with external controls, such as illumination. Herein, we expose several design ...
Eumelanin for nature-inspired UV-absorption enhancement of plastics
(Wiley, 2019-02-06)
In the human body, the black-brown biopigment eumelanin blocks the harmful
ultraviolet (UV) radiation. In the plastics industry, additives are often added to polymers to
increase their UV-absorption properties. We herein ...
Covalently crosslinked mussel byssus protein-based materials with tunable properties
(Wiley, 2018-03-01)
Mussels’ anchoring threads, named byssus, are collagen-rich fibers with outstanding mechanical properties. Our previous work has shown the possibility of producing a byssus protein hydrolyzate with good film-forming ability, ...
Triazine‐based molecular glasses frustrate the crystallization of barbiturates
(Royal Society of Chemistry, 2019-02-05)
Hydrogen bonding is a key element of supramolecular chemistry and is often used in crystal engineering to direct crystal packing. In particular, systems where motifs with multiple hydrogen (H) bonds are present, such as ...